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Single molecule nanocar with functional wheels driven by electron tunneling

The cover of the November 10, 2011 issue of Nature featured a new, 4-wheel drive, electric nanocar, only four by two nanometers in size. Among its shortcomings, however, is the fact that each wheel requires a a “refueling” from an STM tip each half revolution. Access to the full text research article requires a subscription or purchase, but the freely available abstract and supplementary information include four movies showing STM images of the nanocar “speeding” along the copper surface. ScienceDaily describes the result based on this press release from a Swiss research institute Empa “The smallest electric car in the world

Reduced to the max: the emission-free, noiseless 4-wheel drive car, jointly developed by Empa researchers and their Dutch colleagues, represents lightweight construction at its most extreme. The nano car consists of just a single molecule and travels on four electrically-driven wheels in an almost straight line over a copper surface.

… scientists at the University of Groningen and at Empa have successfully taken “a decisive step on the road to artificial nano-scale transport systems”. They have synthesised a molecule from four rotating motor units, i.e. wheels, which can travel straight ahead in a controlled manner. “To do this, our car needs neither rails nor petrol; it runs on electricity. It must be the smallest electric car in the world – and it even comes with 4-wheel drive” comments Empa researcher Karl-Heinz Ernst.

Range per tank of fuel: still room for improvement
The downside: the small car, which measures approximately 4×2 nanometres – about one billion times smaller than a VW Golf – needs to be refuelled with electricity after every half revolution of the wheels – via the tip of a scanning tunnelling microscope (STM). Furthermore, due to their molecular design, the wheels can only turn in one direction. “In other words: there’s no reverse gear”, says Ernst, who is also a professor at the University of Zurich, laconically.

According to its “construction plan” the drive of the complex organic molecule functions as follows: after sublimating it onto a copper surface and positioning an STM tip over it leaving a reasonable gap, Ernst’s colleague, Manfred Parschau, applied a voltage of at least 500 mV. Now electrons should “tunnel” through the molecule, thereby triggering reversible structural changes in each of the four motor units. It begins with a cis-trans isomerisation taking place at a double bond, a kind of rearrangement – in an extremely unfavourable position in spatial terms, though, in which large side groups fight for space. As a result, the two side groups tilt to get past each other and end up back in their energetically more favourable original position – the wheel has completed a half turn. If all four wheels turn at the same time, the car should travel forwards. At least, according to theory based on the molecular structure.

To drive or not to drive – a simple question of orientation
And this is what Ernst and Parschau observed: after ten STM stimulations, the molecule had moved six nanometres forwards – in a more or less straight line. “The deviations from the predicted trajectory result from the fact that it is not at all a trivial matter to stimulate all four motor units at the same time”, explains “test driver” Ernst.

Another experiment showed that the molecule really does behave as predicted. A part of the molecule can rotate freely around the central axis, a C-C single bond – the chassis of the car, so to speak. It can therefore “land” on the copper surface in two different orientations: in the right one, in which all four wheels turn in the same direction, and in the wrong one, in which the rear axle wheels turn forwards but the front ones turn backwards – upon excitation the car remains at a standstill. Ernst und Parschau were able to observe this, too, with the STM.

Therefore, the researchers have achieved their first objective, a “proof of concept”, i.e. they have been able to demonstrate that individual molecules can absorb external electrical energy and transform it into targeted motion. The next step envisioned by Ernst and his colleagues is to develop molecules that can be driven by light, perhaps in the form of UV lasers.

Despite any shortcomings as far as practical transport across a surface, this achievement is remarkable in that the nanocar is not moved by being passively dragged across the surface by the STM tip, but rather the STM tip delivers charge to four functional units, inducing in each a conformation change that causes the movement. The motion they observed—six nanometers after ten steps—is almost exactly what they had predicted from theoretical considerations.

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